This is just an example of how to calculate the radioactivity of an isotope from its halflife.
Uranium 238 has a halflife of 4.468×109 years (4,468,000,000years). This is 4.468×109 x 365.25 x 24 x 60 x 60 = 1.41×1017 seconds.
We can now calculate the decay constant (i.e. the number of decays per second) using the formula derived in Rates of Decay:
Rearranging we get
So we get a decay constand of ln(2) / 1.41×1017 =4.916×10-18 per second.
We now want to work out how many atoms there are in 1 tonne (1,000Kg = 1×106g) of Uranium 238. We know that 238g of U-238 contains 6.022×1023 atoms from the definition of atomic mass.
Therefore 1 tonne contains 1×106/238 x 6.022×1023 = 2.53 x 1027 atoms. Its activity would therefore be 2.53 x 1027 x 4.916×10-18 = 1.24×1010 becquerel.
However the decay product – Thorium – 234 is not stable (halflife 24 days) and decays via รยฒ decay to Pa-234 which undergoes รยฒ decay (halflife 1.17 seconds) to U-234 (halflife 240,00years). So you get many more emissions from on U-238 atom decaying than just the one รยฑ particle you might expect.
I would assume that that there is some U-234 in fresh nuclear fuel. However it is likely that its decay product Th-230 (halflife 77,000 years) was removed during the chemical separation of the uranium from the ore. It will take some time for the Th-230 to build up to such an extent that its decay products add considerably to the activity of the U-238.
We would expect the U-238,ร Th-234, Pa-234, U-234 and Th-230 to be in secular equilibrium in the fresh fuel i.e. their activities to be the same.
Therefore for every U-238 decay we get
U-238 | รยฑ,รยณ |
Th-234 | รยฒ,รยณ |
Pa-234 | รยฒ,รยณ |
U-234 | รยฑ,รยณ |
a total of eight emissions.
Leave a Reply